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Hello, sir How can we start WCF application in visual studio 2010?
What do you mean by start? Start designing, developing, running? Please think about what you are trying to do and clarify your question.
One of these days I'm going to think of a really clever signature.
Menu File->New->Project, Select and Expand Visual C#, Select WCF... What kind of WCF-project you want depends on your needs. Ask MSDN or Google for details and comparison.